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  • #230218
    Avatar of ElinaElina
    Participant

    I’m having trouble understanding what activated manganese dioxide is. If anyone knows a good way to oxidize allyl alcohol using MnO₂ (I’m trying to synthesize the corresponding alcohol in my lab), I’d be very grateful.

    #230243
    Avatar of Jennifer HarperJennifer Harper
    Participant

    When people talk about “active manganese dioxide”, they usually mean that the content was specially treated to increase its oxidation activity. Regular MNO₂ can be quite inactive, especially when wet or crystalline. The active manganese dioxide, however, has a more porous and dry powder with several reactive sites on its surface. It is ideal for oxidizing alleil alcohol manganese dioxide . It works well with alile and benzel alcohol, converting them into this aldehyde or ketone.

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